|
Chemical
Identity
|
Chemical
Name
|
CARBON
DIOXIDE
|
|
Chemical
Classification
|
Inorganic
gas
|
|
Synonyms
|
Carbonic
Acid Gas, Carbonic Anhydride
|
|
Formula
|
CO2
|
|
CAS
Number
|
124-38-9
|
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UN
Number
|
1013
|
|
|
Specification
of Liquid Carbon Dioxide
Applications
Safety
precautions
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| |
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Regulated
Identification
|
Shipping
Name
|
Carbon
Dioxide
|
|
Codes
/ Label
|
Class
2
|
|
Hazardous
waste ID No
|
17
|
|
Hazchem
Code
|
2
X E
|
|
|
| |
|
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Hazardous
Ingredients
|
|
| |
|
|
Physical/Chemical
Data
|
Boiling
Point / Range Decomp
|
Subtimes
oC
|
|
Melting
/ freezing Point
|
-78.5
oC
|
|
Vapour
Density (Air=1)
|
1.53
|
|
Specific
Gravity
|
1.56
at
|
|
(Water=1)
|
-79
C (Liq)
|
|
Physical
State
|
Liquefied
Compr. gas
|
|
Vapour
Pressure @ 35 oC
|
105
mm Hg at -120 oC
|
|
Solubility
in water at 30 o
|
Slightly
Soluble
|
|
PH
|
Not
pertiment
|
|
Appearance
|
Colourless
gas
|
|
Odour
|
Odourless
|
|
Others
|
Absorbed
by alkaline solutions, less soluble in alcohol
|
|
|
| |
|
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Fire
/ Explosion Hazard Data
|
Flammability
|
No
|
|
TDG
Flammability
|
N.A.
|
|
Lower
Explosive Limit
|
Not
pertinent %
|
|
Upper
Explosive Limit
|
Not
pertinent %
|
|
Flash
Point oC
|
Not
pertinent (OC)
|
|
Autoignition
Temperature oC
|
Not
pertinent
|
|
Explosion
Sensitivity to Impact
|
Stable
|
|
Explosion
Sensitivity to Static Electricity
|
Stable
|
|
Hazardous
Combustion Products
|
Not
pertinent
|
|
Hazardous
Polymerization
|
Will
not occur
|
|
Combustible
Liquid
|
No
|
|
Flammable
Material
|
No
|
|
Pyrophoric
Material
|
No
|
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Explosive
Material
|
No
|
|
Oxidiser
|
No
|
|
Organic
Peroxide
|
No
|
|
Corrosive
Material
|
No
|
|
Others
|
-
|
|
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| |
|
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Reactivity
Data
|
Chemical
Stability
|
Stable
|
|
Incompatibility
with other material
|
With
chemically active metals such as Sodium, Postassium,
hot Titanium
|
|
Reactivity
|
Reacts
vigorously with (Al + Na2, O2), Cs2. O. Mg (C2 H3) 2 Li (Mg + Na2
O2), K, Na, Na2 C2, NaK, Ti
|
|
Hazardous
Reaction Products
|
Not
available
|
|
|
| |
|
|
Health
Hazard Data
|
Routes
of entry
|
Inhalation,
Skin and Eyes
|
|
Effects
of Exposure / Symptoms
|
Inhalation
causes increased respiration rate, headache, subtle physiological
changes for upto 5% conc. And prolonged exposures. Higher concentrations
can cause unconsciouness and death. Solid can cause cold contact
burns. Liquid or cold gas cause freezing injury to skin or eyes
similar to burn.
|
|
Emergency
Treatment
|
Inhalation
: Move the victim to fresh air area. Skin : Treat
burns from contact with solid in the same way as frastbite. Eyes
: Irrigate with plenty of water for 15 mins. Seek medical
aid immediately.
|
|
LD50
(Oral-rat)
|
Not
listed
|
|
mg/kg
|
|
|
Permissible
Exposure Limit
|
Not
listed
|
|
ppm
|
Not
listed mg/m3
|
|
TLV
(ACGIH)
|
5000
|
|
ppm
|
9000
mg/m3
|
|
STEL
|
30000
|
|
ppm
|
54000
mg/m3
|
|
Odour
Threshold
|
Odourless
|
|
ppm
|
Odourless
mg/m3
|
|
NFPA
Hazard Signals
|
Health
= -, Flammability = -, Reactivity = -, Special = -
|
|
|
| |
|
|
Preventive
Measures
|
Personal
Protective Equipment
|
Avoid
contact with liquid or Solid.
Provide self-contained breathing apparatus in excessively high Co2
conc areas. For handling liquid or solid, wear face shield, or safety
goggles, insulated gloves, long sleeved shirt, and trousers worn
outside.
|
|
Handling
& Storage Precautions
|
Keep
in a dry cool place away from heat.
|
|
|
| |
|
|
Emergency
/ First aid Measures
|
FIRE
- Fire Extinguishing Media
|
Not
flammable
|
|
Special
Procedure Unusual Hazards
|
Keep
the containers cool by spraying water if exposed to fire or heat.
Containers may explode in fire.
|
|
EXPOSURE
- First Aid Measures
|
Inhalation
: Remove the victim to fresh air area. Skin : Treat
burns from contact with solid in the same way as frostbite. Eyes
: Irrigate with plenty of water for 15 mins. and immediately
seek medical aid.
|
|
Antidotes
/ Dosages
|
Not
available
|
|
|
| |
|
|
Spills
|
Steps
to be taken
|
Shut
off leaks if without risk. Allow to evaporate slowly.
|
|
Waste
Disposal Method
|
Allow
the liquid or solid to evaporate under control.
|
|
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|
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Additional
Information / References
|
LCLo
|
10000
ppm / 1M (ihl-hmn). An asphyxiant. Contact of carbon dioxide snow
with skin can cause burns. Dusts of Magnesissm, Zirconlsam, Titanium
and some Magnesium. Aluminium alloys ignite and then explode in
Co2 atmosphere. Several bulk metals will burn in Co2, atmosphere.
Humans cannot breathe air containing more than 10% Co2 without losing
consciousness.
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| The information
contained herein is based on technical data and tests, which we believe
to be reliable. However, we assume no responsibility for results obtained
or damage, if any, incurred through the application of data given, since
conditions of use are outside our control. |
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